Sodium hydride → HCID 57837615, compound

HRID 2264337Notes

Reaction equation

HRID 2264337 reaction equation
Cl[C:2]1[C:7]([C:8]([F:11])([F:10])[F:9])=[CH:6][C:5]([N+:12]([O-:14])=[O:13])=[CH:4][C:3]=1[N+:15]([O-:17])=[O:16].[CH2:18]([O:25][C:26](=[O:38])[CH2:27][C:28]([O:30][CH2:31][C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=1)=[O:29])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1.[H-].[Na+]>>[CH2:31]([O:30][C:28](=[O:29])[CH:27]([C:2]1[C:7]([C:8]([F:11])([F:10])[F:9])=[CH:6][C:5]([N+:12]([O-:14])=[O:13])=[CH:4][C:3]=1[N+:15]([O-:17])=[O:16])[C:26]([O:25][CH2:18][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)=[O:38])[C:32]1[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=1

Participants

4

Reactant 3

HCID 24758Sodium hydrideHCID 67851Benzene, 2-chloro-1,5-dinitro-3-(trifluoromethyl)-HCID 84754Dibenzyl malonate

Product 1

HCID 57837615HCID 57837615, compound

Procedure

2-Chloro-1,5-dinitro-3-(trifluoromethyl)benzene was treated with malonic acid dibenzyl ester in the presence of sodium hydride to obtain [2,4-dinitro-6-(trifluoromethyl)phenyl]malonic acid dibenzyl ester.

Sources & evidence

ORD record
ord-6bdf41cad777453f9d5d8c278581a0e9
Source dataset
uspto-grants-2010_12
Patent number
US07855198B2

Reaction notes

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