4-Methylpyridine → 1-(4-Acetoxybutyl)-4-methyl-pyridinium iodide

HRID 2264860Notes

Reaction equation

HRID 2264860 reaction equation
[N:1]1[CH:6]=[CH:5][C:4]([CH3:7])=[CH:3][CH:2]=1.[I:8][CH2:9][CH2:10][CH2:11][CH2:12][O:13][C:14](=[O:16])[CH3:15]>CCOCC>[I-:8].[C:14]([O:13][CH2:12][CH2:11][CH2:10][CH2:9][N+:1]1[CH:6]=[CH:5][C:4]([CH3:7])=[CH:3][CH:2]=1)(=[O:16])[CH3:15]

Participants

4

Reactant 2

HCID 79634-MethylpyridineHCID 27334054-Iodobutyl acetate

Product 1

HCID 687814631-(4-Acetoxybutyl)-4-methyl-pyridinium iodide

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

10 mmol (0.93 g) γ-picoline and 10 mmol (2.42 g) 4-iodobutylacetate are heated 4 h at 120° C. and after cooling repeatedly stirred with ether, decanted a finally dried in vacuum.

Workup

  1. temperatureafter cooling repeatedly
  2. customdecanted
  3. customa finally dried in vacuum

Sources & evidence

ORD record
ord-a7c4bc6d527b4e8d97a03b4f193d3b19
Source dataset
uspto-grants-2010_12
Patent number
US07855293B2

Reaction notes

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