HRID2265113

反应详情

EQUATION

反应方程式

REACTANTS

反应物

反应SMILES：COc1ccc(P2(=S)SP(=S)(c3ccc(OC)cc3)S2)cc1

HCID87949

p-Anisyldithiophosphonic anhydride

C14H14O2P2S4

反应SMILES：CCOC(=O)/C=C/c1ccc(NC(=O)c2cc([Si](C)(C)C)cc([Si](C)(C)C)c2)nc1

HCID86644273

未命名化合物

反应SMILES：CCOC(=O)C=Cc1ccc(NC(=S)c2cc([Si](C)(C)C)cc([Si](C)(C)C)c2)cc1

HCID86644287

未命名化合物

PRODUCTS

产物

反应SMILES：CCOC(=O)/C=C/c1ccc(NC(=S)c2cc([Si](C)(C)C)cc([Si](C)(C)C)c2)nc1

HCID86644288

未命名化合物

收率 92.6%

PROCEDURE

实验过程

Using Compound 18a (135 mg) and Lawesson's reagent (86.7 mg), Compound 18b (90.7 mg, 65%) was obtained as a yellow solid in the same manner as Compound 17b was synthesized.

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-ac54bc79ab454b0891e405f8a3689c7c
来源数据集: uspto-grants-2010_12
DOI: 10.6084/m9.figshare.5104873.v1
专利号: US07855300B2
来源说明: uspto-grants-2010_12

反应SMILES

[CH3:1][Si:2]([CH3:30])([CH3:29])[C:3]1[CH:4]=[C:5]([CH:22]=[C:23]([Si:25]([CH3:28])([CH3:27])[CH3:26])[CH:24]=1)[C:6]([NH:8][C:9]1[N:14]=[CH:13][C:12](/[CH:15]=[CH:16]/[C:17]([O:19][CH2:20][CH3:21])=[O:18])=[CH:11][CH:10]=1)=O.COC1C=CC(P2(SP(C3C=CC(OC)=CC=3)(=S)S2)=[S:40])=CC=1.C[Si](C)(C)C1C=C(C(NC2C=CC(C=CC(OCC)=O)=CC=2)=S)C=C([Si](C)(C)C)C=1>>[CH3:1][Si:2]([CH3:30])([CH3:29])[C:3]1[CH:4]=[C:5]([C:6]([NH:8][C:9]2[N:14]=[CH:13][C:12](/[CH:15]=[CH:16]/[C:17]([O:19][CH2:20][CH3:21])=[O:18])=[CH:11][CH:10]=2)=[S:40])[CH:22]=[C:23]([Si:25]([CH3:28])([CH3:27])[CH3:26])[CH:24]=1