TIBA cyclohexane → 2,3,5-Triiodobenzoic acid

HRID 2267213Notes

Reaction equation

HRID 2267213 reaction equation
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].C1CCCCC1>C1(C)C=CC=CC=1>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]

Participants

3

Reactant 1

HCID 131728537TIBA cyclohexane

Product 1

HCID 69482,3,5-Triiodobenzoic acid

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

39.1 mL of TIBA/cyclohexane solution (113 g/L) were mixed with 2.8 mL of MAO/toluene solution to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 1 h at room temperature and transferred into a 50 mL Schlenk flask containing 21.1 mg of C1. This solution was diluted with 6.78 mL of cyclohexane to give an orange solution of concentration 100 gTOT/L and 0.99 gmetallocene/L.

Sources & evidence

ORD record
ord-2e9c7f07231247999bce512b318d0c27
Source dataset
uspto-grants-2010_12
Patent number
US07858717B2

Reaction notes

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