Potassium Carbonate → HCID 21910016, compound

HRID 2268707Notes

Reaction equation

HRID 2268707 reaction equation
[C:1]1([CH3:15])[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.C(=O)([O-])[O-].[K+].[K+].Br[C:23]1[C:40]2[C:41]3[C:26]([C:27]4[CH:28]=[CH:29][CH:30]=[C:31]5[C:42]=4[C:35]([C:36]=3[CH:37]=[CH:38][CH:39]=2)=[C:34]2[CH:43]=[CH:44][CH:45]=[CH:46][C:33]2=[CH:32]5)=[CH:25][CH:24]=1>O.[Cu]>[C:11]1([CH3:14])[CH:12]=[CH:13][C:8]([N:7]([C:23]2[C:40]3[C:41]4[C:26]([C:27]5[CH:28]=[CH:29][CH:30]=[C:31]6[C:42]=5[C:35]([C:36]=4[CH:37]=[CH:38][CH:39]=3)=[C:34]3[CH:43]=[CH:44][CH:45]=[CH:46][C:33]3=[CH:32]6)=[CH:25][CH:24]=2)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:9][CH:10]=1

Participants

6

Reactant 3

HCID 11430Potassium CarbonateHCID 69293Benzenamine, 4-methyl-N-(4-methylphenyl)-HCID 21910017HCID 21910017, compound

Product 1

HCID 21910016HCID 21910016, compound

Reagents, catalysts & solvents 2

HCID 23978CopperCatalystHCID 962WaterSolvent

Procedure

Then, di-p-tolylamine, potassium carbonate, and copper power were added to the thus obtained bromobenzo[a]perylene. This mixture stood still for reaction at 200 degrees centigrade for thirty hours. After reactant solution was diluted with water, reactant was extracted by chloroform. Thereafter, the reactant was refined in a conventional manner to thereby obtain di-p-tolylaminobenzo[a]perylene.

Workup

  1. customThis mixture stood still for reaction at 200 degrees centigrade for thirty hours
  2. extractionwas extracted by chloroform

Sources & evidence

ORD record
ord-e11bd982373541b7bbaba6074acb16f3
Source dataset
uspto-grants-2001_12
Patent number
US06329083B1

Reaction notes

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