HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Bromide → HCID 18347150, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Bromide | HCID 260 | — |
| Reactant | 5,6-Dimethyl-1-indanone | HCID 27878 | — |
| Reactant | Thioacetamide | HCID 2723949 | — |
| Reactant | HCID 18347144 | HCID 18347144 | — |
| Reactant | HCID 18347158 | HCID 18347158 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | HCID 18347150 | HCID 18347150 | — |
Reaction Steps
5,6-Dimethylindan-1-one is converted as described above for the other indan-1-ones into 2-bromo-5,6-dimethylindan-1-one. This is reacted with an equivalent amount of thioacetamide in acetone. The precipitate consisting of the hydrobromide of 2,5,6-trimethyl-8,8a-dihydroindeno-[1,2-d]thiazol-3a-ol is heated in glacial acetic acid and affords, after removal of the solvent and treatment with diisopropyl ether, 2,5,6-trimethyl-8H-indeno[1,2-d]thiazole hydrobromide with a melting point of 290° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06329407B1 |
| Source dataset | uspto-grants-2001_12 |
| ORD ID | ord-8cd861f72bd4437a984e41443941b751 |
| Source note | uspto-grants-2001_12 |