Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Diethyl Malonate | HCID 7761 | — |
| Reactant | Magnesium | HCID 5462224 | — |
| Catalyst | Carbon Tetrachloride | HCID 5943 | — |
| Solvent | Toluene | HCID 1140 | — |
Reaction Steps
Separately, 0.9 ml of absolute ethanol and two drops of carbon tetrachloride were added to 0.4 g of metallic magnesium. When a reaction began, a mixture of 2.6 ml of diethyl malonate, 1.6 ml of absolute ethanol and 6 ml of toluene was added dropwise to the reaction mixture at a temperature not higher than 60° C., followed by stirring at 60° C. for 1 hour to give ethoxymagnesium ethyl malonate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06333431B1 |
|---|
| Source dataset | uspto-grants-2001_12 |
|---|
| ORD ID | ord-8b1556e51b3c45ada3a4335d56bd4788 |
|---|
| Source note | uspto-grants-2001_12 |
|---|
