Cyclopropylamine → HCID 131733379, compound

Participants

Reaction Steps

In an argon atmosphere, 6.22 g (26.7 mmol) of Si(tBuNCHCHNtBu)(H)Cl was dissolved in 30 mL of hexane and after adding 3.14 g (56.0 mmol) of cyclopropylamine, the mixture was stirred at room temperature for 3 hours. Insoluble matters produced were separated by filtration, and the solvent was removed by distillation from the filtrate under atmospheric pressure. The obtained residue was distilled under reduced pressure (distillation temperature: 100° C./3.7×102 Pa) to obtain 1,3-di-tert-butyl-2-cyclopropylamino-1,3-diaza-2-silacyclopent-4-ene (Si(tBuNCHCHNtBu)(H)NHcPr) as a colorless liquid (yielded amount: 6.07 g, yield: 90%).

Provenance & Evidence