Sodium Bicarbonate → HCID 66769631, compound

HRID 2273363Notes

Reaction equation

HRID 2273363 reaction equation
[CH3:1][C:2]1[CH:26]=[C:25]([CH3:27])[CH:24]=[C:23]([CH3:28])[C:3]=1[C:4]([P:6]([CH2:19][C:20]([OH:22])=[O:21])([C:8](=[O:18])[C:9]1[C:14]([CH3:15])=[CH:13][C:12]([CH3:16])=[CH:11][C:10]=1[CH3:17])=[O:7])=[O:5].C(=O)([O-])O.[Na+:33]>O>[CH3:15][C:14]1[CH:13]=[C:12]([CH3:16])[CH:11]=[C:10]([CH3:17])[C:9]=1[C:8]([P:6]([C:4](=[O:5])[C:3]1[C:23]([CH3:28])=[CH:24][C:25]([CH3:27])=[CH:26][C:2]=1[CH3:1])([CH2:19][C:20]([O-:22])=[O:21])=[O:7])=[O:18].[Na+:33]

Participants

4

Reactant 2

HCID 516892Sodium BicarbonateHCID 66769632HCID 66769632, compound2×

Product 1

HCID 66769631HCID 66769631, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

2-(bis(2,4,6-trimethylbenzoyl)phosphoryl)acetic acid (example 18b) (0.1 g, 0.25 mmol, 1 eq.) is suspended in distilled water (2 ml) and sodium hydrogencarbonate (21.0 mg, 0.25 mmol, 1 eq.) is added. A clear pale yellow solution is obtained. After removing the water in vacuo at room temperature, a pale yellow crystalline powder is isolated (Yield: quantitative). It is evident that the same procedure can be performed to synthesise other alkali salts of 2-(bis(2,4,6-trimethylbenzoyl)phosphoryl)acetic acid from carbonates or hydrogen-carbonates (e.g. with potassium hydrogen carbonate, or lithium carbonate).

Workup

  1. customA clear pale yellow solution is obtained
  2. customAfter removing the water in vacuo at room temperature
  3. customa pale yellow crystalline powder is isolated (Yield: quantitative)

Sources & evidence

ORD record
ord-cff69881fb304aa78e7021d4f91affc4
Source dataset
uspto-grants-2015_09
Patent number
US09120900B2

Reaction notes

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