反应详情

In a stream of argon, 1.29 g (5.81 mmol) of 9-phenanthreneboronic acid, 1.20 g (2.42 mmol) of 2-(3,5-dibromophenyl)-4,6-di-p-tolyl-1,3,5-triazine and 67.9 mg (0.097 mmol) of dichlorobis(triphenylphosphine)palladium were suspended in 108 mL of tetrahydrofuran, and the temperature of the obtained suspension was elevated to 70° C. 4.53 mL (18.2 mmol) of an aqueous 4N NaOH solution was gradually added dropwise to the suspension, and the obtained mixture was distilled under reflux for 2 hours. Further, 0.11 g (0.50 mmol) of 9-phenanthreneboronic acid was added, and the obtained mixture was distilled under reflux for 2 hours. The resultant reaction mixture was left to stand to room temperature, and then distilled under a reduced pressure to remove all volatile materials. Methanol was added to the concentrate, and the thus-deposited solid was collected by filtration. The thus-obtained crude product was recrystallized from o-xylene to give 0.74 g of the target 2-[3,5-di(9-phenanthryl)-phenyl]-4,6-di-p-tolyl-1,3,5-triazine as grayish white solid (yield: 44%).

1. customwas elevated to 70° C
2. distillationthe obtained mixture was distilled
3. temperatureunder reflux for 2 hours
4. distillationthe obtained mixture was distilled
5. temperatureunder reflux for 2 hours
6. customThe resultant reaction mixture
7. waitwas left
8. customto stand to room temperature
9. distillationdistilled under a reduced pressure
10. customto remove all volatile materials
11. additionMethanol was added to the concentrate
12. filtrationthe thus-deposited solid was collected by filtration
13. customThe thus-obtained crude product
14. customwas recrystallized from o-xylene