HRID2282080

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-].[Ti+4]

HCID21801

Titanium(IV) n-butoxide

C16H36O4Ti

HCID86656680

未命名化合物

PRODUCTS

生成物

结构：CCCCOP(=O)(CC)CCC(=O)[O-].CCCCOP(=O)(CC)CCC(=O)[O-].CCCCOP(=O)(CC)CCC(=O)[O-].CCCCOP(=O)(CC)CCC(=O)[O-].[Ti+4]

HCID131733516

未命名化合物

收率 97.4%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

222 g (1 mol) of 3-(ethylbutoxyphosphinyl)propionic acid (produced as in Example 13) and 85 g of titanium tetrabutoxide are refluxed in 500 ml of toluene for 40 hours. The resulting butanol is distilled off from time to time with proportions of toluene. The solution formed is subsequently freed of solvent to leave 227 g of 3-(ethylbutoxyphosphinyl)propionic acid titanium salt.

WORKUP

后处理

distillationThe resulting butanol is distilled off from time to time with proportions of toluene
customThe solution formed

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8ba86ee21e7d4696843c520808234b5c
来源数据集: uspto-grants-2015_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US09139714B2
来源说明: uspto-grants-2015_09

反应 SMILES

[CH2:1]([P:3]([O:10][CH2:11][CH2:12][CH2:13][CH3:14])([CH2:5][CH2:6][C:7]([OH:9])=[O:8])=[O:4])[CH3:2].[O-]CCCC.[O-]CCCC.[O-]CCCC.[O-]CCCC.[Ti+4:35]>C1(C)C=CC=CC=1>[Ti+4:35].[CH2:1]([P:3]([O:10][CH2:11][CH2:12][CH2:13][CH3:14])([CH2:5][CH2:6][C:7]([O-:9])=[O:8])=[O:4])[CH3:2].[CH2:1]([P:3]([CH2:5][CH2:6][C:7]([O-:9])=[O:8])([O:10][CH2:11][CH2:12][CH2:13][CH3:14])=[O:4])[CH3:2].[CH2:1]([P:3]([CH2:5][CH2:6][C:7]([O-:9])=[O:8])([O:10][CH2:11][CH2:12][CH2:13][CH3:14])=[O:4])[CH3:2].[CH2:1]([P:3]([CH2:5][CH2:6][C:7]([O-:9])=[O:8])([O:10][CH2:11][CH2:12][CH2:13][CH3:14])=[O:4])[CH3:2]