N,N-dimethyl-p-phenylenediamine → HCID 67113294, compound

HRID 2284151Notes

Reaction equation

HRID 2284151 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]2[C:10](=[CH:11][CH:12]=1)[NH:9][C:8]([C:13]1[CH:18]=[CH:17][C:16]([C:19](OC)=[O:20])=[CH:15][CH:14]=1)=[CH:7]2)([O-])=O.[CH3:23][N:24]([CH3:32])[C:25]1[CH:31]=[CH:30][C:28]([NH2:29])=[CH:27][CH:26]=1.[CH3:33][N:34]([CH3:44])[C:35]1[CH:43]=[CH:42][C:38]([C:39](O)=[O:40])=[CH:37][CH:36]=1>>[CH3:33][N:34]([CH3:44])[C:35]1[CH:43]=[CH:42][C:38]([C:39]([NH:1][C:4]2[CH:5]=[C:6]3[C:10](=[CH:11][CH:12]=2)[NH:9][C:8]([C:13]2[CH:14]=[CH:15][C:16]([C:19](=[O:20])[NH:29][C:28]4[CH:30]=[CH:31][C:25]([N:24]([CH3:32])[CH3:23])=[CH:26][CH:27]=4)=[CH:17][CH:18]=2)=[CH:7]3)=[O:40])=[CH:37][CH:36]=1

Participants

4

Reactant 3

HCID 7472N,N-dimethyl-p-phenylenediamineHCID 120924-(Dimethylamino)benzoic acidHCID 44577835HCID 44577835, compound

Product 1

HCID 67113294HCID 67113294, compound

Procedure

Compound 246 was prepared according to the procedure similar to that described in Scheme III from 5-nitro-2-(4-methoxycarbonylphenyl)indole, 4-dimethylaminoaniline, and 4-dimethylaminobenzoic acid. [M+H]+ calcd for C31H30N6O2: 519.25; found: 519.59.

Sources & evidence

ORD record
ord-8e4c7dc3d468440aa7d0274aa9101c1d
Source dataset
uspto-grants-2015_09
Patent number
US09144557B2

Reaction notes

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