P-Phenylenediamine → HCID 67686804, compound

HRID 2284265Notes

Reaction equation

[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[N:10]=[C:9]([C:11]3[CH:19]=[CH:18][C:14]([C:15]([OH:17])=O)=[CH:13][CH:12]=3)[NH:8][C:7]=2[CH:20]=1.[C:21]1([NH2:28])[CH:26]=[CH:25][C:24]([NH2:27])=[CH:23][CH:22]=1.[CH3:29][N:30]([CH3:40])[C:31]1[CH:39]=[CH:38][C:34]([C:35](O)=[O:36])=[CH:33][CH:32]=1>>[CH3:29][N:30]([CH3:40])[C:31]1[CH:39]=[CH:38][C:34]([C:35]([NH:27][C:24]2[CH:25]=[CH:26][C:21]([NH:28][C:15](=[O:17])[C:14]3[CH:13]=[CH:12][C:11]([C:9]4[NH:8][C:7]5[CH:20]=[C:3]([O:2][CH3:1])[CH:4]=[CH:5][C:6]=5[N:10]=4)=[CH:19][CH:18]=3)=[CH:22][CH:23]=2)=[O:36])=[CH:33][CH:32]=1

Participants

Reactant 3

HCID 7814P-Phenylenediamine

HCID 120924-(Dimethylamino)benzoic acid

HCID 4915284HCID 4915284, compound

Product 1

HCID 67686804HCID 67686804, compound

Procedure

Compound 625 was prepared according to the procedure similar to that described in Scheme III from 4-(6-methoxy-1H-benzo[d]imidazol-2-yl)benzoic acid, 1,4-phenylenediamine, and 4-dimethylaminobenzoic acid. [M+H]+ calcd for C30H27N5O3: 506.21; found: 506.05.

Sources & evidence

ORD record: ord-32bcea7b1c2d496aa69e26e6362c9b54
Source dataset: uspto-grants-2015_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09144557B2

Reaction notes

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