HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → Palladium tetraphenylporphyrin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Palladium Chloride | HCID 24290 | — |
| Reactant | 5,10,15,20-Tetraphenyl-21,22-dihydroporphyrin | HCID 70186 | — |
| Solvent | Water | HCID 962 | — |
| Product | Palladium tetraphenylporphyrin | HCID 136447763 | — |
Reaction Steps
Palladium tetraphenylporphyrin is prepared according to the experimental method described by A. D. Adler, F. R. Longo, F. Kampas and J. Kim, J. Inorg. Nucl. Chem. Vol. 32, p. 2443 (1970). To 300 ml of boiling dimethylformamide are added 3 g of tetraphenylporphyrin. After dissolution is effected, 0.9 g of palladium chloride is added. The mixture is refluxed for 10 minutes, then cooled in an ice bath and poured into 300 ml of water. The precipitate is filtered, washed with water and dried.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04323515 |
| Source dataset | uspto-grants-1982_04 |
| ORD ID | ord-f35e1b8211c04834a632f5f8eeb12f1b |
| Source note | uspto-grants-1982_04 |