HRID2285452

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6228

N,N-Dimethylformamide

C3H7NO

HCID24290

未命名化合物

结构：C1=Cc2nc1c(-c1ccccc1)c1nc(c(-c3ccccc3)c3ccc([nH]3)c(-c3ccccc3)c3ccc([nH]3)c2-c2ccccc2)C=C1

HCID70186

未命名化合物

PRODUCTS

生成物

结构：C1=Cc2nc1c(-c1ccccc1)c1ccc([nH]1)c(-c1ccccc1)c1nc(c(-c3ccccc3)c3ccc([nH]3)c2-c2ccccc2)C=C1.[Pd]

HCID136447763

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

PROCEDURE

实验过程

Palladium tetraphenylporphyrin is prepared according to the experimental method described by A. D. Adler, F. R. Longo, F. Kampas and J. Kim, J. Inorg. Nucl. Chem. Vol. 32, p. 2443 (1970). To 300 ml of boiling dimethylformamide are added 3 g of tetraphenylporphyrin. After dissolution is effected, 0.9 g of palladium chloride is added. The mixture is refluxed for 10 minutes, then cooled in an ice bath and poured into 300 ml of water. The precipitate is filtered, washed with water and dried.

WORKUP

后处理

dissolutionAfter dissolution
temperatureThe mixture is refluxed for 10 minutes
temperaturecooled in an ice bath
filtrationThe precipitate is filtered
washwashed with water
customdried

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-f35e1b8211c04834a632f5f8eeb12f1b
来源数据集: uspto-grants-1982_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04323515
来源说明: uspto-grants-1982_04

反应 SMILES

CN(C)C=O.[CH:6]1[CH:7]=[CH:8][C:9]([C:12]2[C:13]3[NH:17][C:16]([C:18]([C:48]4[CH:49]=[CH:50][CH:51]=[CH:52][CH:53]=4)=[C:19]4[CH:47]=[CH:46][C:21](=[C:22]([C:40]5[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=5)[C:23]5[CH:39]=[CH:38][C:25](=[C:26]([C:32]6[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=6)[C:27]6[CH:28]=[CH:29][C:30]=2[N:31]=6)[N:24]=5)[NH:20]4)=[CH:15][CH:14]=3)=[CH:10][CH:11]=1.[Pd:54](Cl)Cl>O>[C:48]1([C:18]2[C:16]3[NH:17][C:13](=[CH:14][CH:15]=3)[C:12]([C:9]3[CH:10]=[CH:11][CH:6]=[CH:7][CH:8]=3)=[C:30]3[N:31]=[C:27]([CH:28]=[CH:29]3)[C:26]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[C:25]3[NH:24][C:23]([CH:39]=[CH:38]3)=[C:22]([C:40]3[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=3)[C:21]3=[N:20][C:19]=2[CH:47]=[CH:46]3)[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=1.[Pd:54]