Dimethylformamide → Palladium tetraphenylporphyrin

HRID 2285452Notes

Reaction equation

HRID 2285452 reaction equation
CN(C)C=O.[CH:6]1[CH:7]=[CH:8][C:9]([C:12]2[C:13]3[NH:17][C:16]([C:18]([C:48]4[CH:49]=[CH:50][CH:51]=[CH:52][CH:53]=4)=[C:19]4[CH:47]=[CH:46][C:21](=[C:22]([C:40]5[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=5)[C:23]5[CH:39]=[CH:38][C:25](=[C:26]([C:32]6[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=6)[C:27]6[CH:28]=[CH:29][C:30]=2[N:31]=6)[N:24]=5)[NH:20]4)=[CH:15][CH:14]=3)=[CH:10][CH:11]=1.[Pd:54](Cl)Cl>O>[C:48]1([C:18]2[C:16]3[NH:17][C:13](=[CH:14][CH:15]=3)[C:12]([C:9]3[CH:10]=[CH:11][CH:6]=[CH:7][CH:8]=3)=[C:30]3[N:31]=[C:27]([CH:28]=[CH:29]3)[C:26]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[C:25]3[NH:24][C:23]([CH:39]=[CH:38]3)=[C:22]([C:40]3[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=3)[C:21]3=[N:20][C:19]=2[CH:47]=[CH:46]3)[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=1.[Pd:54]

Participants

5

Reactant 3

HCID 6228DimethylformamideHCID 24290Palladium ChlorideHCID 701865,10,15,20-Tetraphenyl-21,22-dihydroporphyrin

Product 1

HCID 136447763Palladium tetraphenylporphyrin

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Palladium tetraphenylporphyrin is prepared according to the experimental method described by A. D. Adler, F. R. Longo, F. Kampas and J. Kim, J. Inorg. Nucl. Chem. Vol. 32, p. 2443 (1970). To 300 ml of boiling dimethylformamide are added 3 g of tetraphenylporphyrin. After dissolution is effected, 0.9 g of palladium chloride is added. The mixture is refluxed for 10 minutes, then cooled in an ice bath and poured into 300 ml of water. The precipitate is filtered, washed with water and dried.

Workup

  1. dissolutionAfter dissolution
  2. temperatureThe mixture is refluxed for 10 minutes
  3. temperaturecooled in an ice bath
  4. filtrationThe precipitate is filtered
  5. washwashed with water
  6. customdried

Sources & evidence

ORD record
ord-f35e1b8211c04834a632f5f8eeb12f1b
Source dataset
uspto-grants-1982_04
Patent number
US04323515

Reaction notes

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