Hydrogen Bromide → HCID 13409035, compound

HRID 2285611Notes

Reaction equation

HRID 2285611 reaction equation
[Cl:1][C:2]1[C:15]([Cl:16])=[C:14]([C:17](=[O:26])[C:18]2[CH:23]=[CH:22][C:21]([O:24]C)=[CH:20][CH:19]=2)[CH:13]=[CH:12][C:3]=1[O:4][CH:5]([CH3:11])[C:6]([O:8]CC)=[O:7].Br>O>[Cl:1][C:2]1[C:15]([Cl:16])=[C:14]([C:17](=[O:26])[C:18]2[CH:19]=[CH:20][C:21]([OH:24])=[CH:22][CH:23]=2)[CH:13]=[CH:12][C:3]=1[O:4][CH:5]([CH3:11])[C:6]([OH:8])=[O:7]

Participants

4

Reactant 2

HCID 260Hydrogen BromideHCID 70550599HCID 70550599, compound

Product 1

HCID 13409035HCID 13409035, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 19.34 g. of ethyl 2,3-dichloro-4-(4'-methoxybenzoyl)phenoxy-α-methylacetate and 330 ml. of 48% hydrogen bromide was rapidly stirred and refluxed for 211/2 hours. The mixture was cooled in an ice bath and diluted with 415 ml. of water, with stirring. The product was filtered and washed with ice water; m.p. 208°-212°.

Workup

  1. additionA mixture of 19.34 g
  2. temperaturerefluxed for 211/2 hours
  3. temperatureThe mixture was cooled in an ice bath
  4. additiondiluted with 415 ml
  5. filtrationThe product was filtered
  6. washwashed with ice water

Sources & evidence

ORD record
ord-c9bdf4d15d04436f834b8545cb8f1065
Source dataset
uspto-grants-1982_04
Patent number
US04323691

Reaction notes

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