Butanethiol → HCID 20544206, compound

HRID 2285713Notes

Reaction equation

HRID 2285713 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10]Cl)=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2].[CH2:16]([SH:20])[CH2:17][CH2:18][CH3:19]>C(OCC)C>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][S:20][CH2:16][CH2:17][CH2:18][CH3:19])=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 8012ButanethiolHCID 127635554-Nitro-2-trichloromethylbenzenesulfenyl chloride

Product 1

HCID 20544206HCID 20544206, compoundYield 92.1%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

61 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride in 800 ml of diethyl ether is reacted in a stirred apparatus with 18 g of 1-butylmercaptan for 6 hours at 25° C. The completion of the reaction is determined by gas chromatography. After removal of the solvent, there is obtained 66 g (92% of theory) of (4-nitro-2-trichloromethylphenyl)-n-butyl disulfide as a yellow oil.

Workup

  1. customAfter removal of the solvent

Sources & evidence

ORD record
ord-cf198ab545684497b81619fb8349f1d8
Source dataset
uspto-grants-1982_04
Patent number
US04324793

Reaction notes

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