1-Dodecanethiol → (4-Nitro-2-trichloromethylphenyl)-dodecyl disulfide

HRID 2285717Notes

Reaction equation

HRID 2285717 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10]Cl)=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2].[CH2:16]([SH:28])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]>>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][S:28][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 81951-DodecanethiolHCID 127635554-Nitro-2-trichloromethylbenzenesulfenyl chloride

Product 1

HCID 20544208(4-Nitro-2-trichloromethylphenyl)-dodecyl disulfideYield 86%

Procedure

As in Example 1, 61.4 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride is reacted with 40.5 g of dodecyl-mercaptan. There is obtained 81 g (86% of theory) of (4-nitro-2-trichloromethylphenyl)-dodecyl disulfide.

Sources & evidence

ORD record
ord-a39b9df5010d4ca3af6f3256f5778dfd
Source dataset
uspto-grants-1982_04
Patent number
US04324793

Reaction notes

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