Thioglycolic Acid → HCID 20544199, compound

HRID 2285718Notes

Reaction equation

HRID 2285718 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10]Cl)=[C:6]([C:12]([Cl:15])([Cl:14])[Cl:13])[CH:5]=1)([O-:3])=[O:2].[C:16]([OH:20])(=[O:19])[CH2:17][SH:18]>>[C:16]([CH2:17][S:18][S:10][C:7]1[CH:8]=[CH:9][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][C:6]=1[C:12]([Cl:15])([Cl:14])[Cl:13])([OH:20])=[O:19]

Participants

3

Reactant 2

HCID 1133Thioglycolic AcidHCID 127635554-Nitro-2-trichloromethylbenzenesulfenyl chloride

Product 1

HCID 20544199HCID 20544199, compoundYield 85.6%

Procedure

As in Example 1, 61.4 g of 4-nitro-2-trichloromethylbenzenesulfenyl chloride is reacted with 18.4 g of thioglycolic acid. After the solvent has been distilled off and the residue recrystallized from toluene, there is obtained 62 g of carboxymethyldithio-4-nitro-2-trichloromethylbenzene; m.p.: 140° C.

Workup

  1. distillationAfter the solvent has been distilled off
  2. customthe residue recrystallized from toluene

Sources & evidence

ORD record
ord-8ff28fb007b546f3ab681f64afb4f3e8
Source dataset
uspto-grants-1982_04
Patent number
US04324793

Reaction notes

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