Boron trifluoride etherate → HCID 86738340, compound

HRID 2285882Notes

Reaction equation

HRID 2285882 reaction equation
[C:1]([O:4][CH2:5][C@:6]12[CH2:23][CH2:22][C@H:21]3[C@@H:11]([CH2:12][CH2:13][CH:14]4[C@:19]3([CH3:20])[CH2:18][CH2:17][C@H:16](O)[CH2:15]4)[C@H:10]1[CH2:9][CH2:8][CH2:7]2)(=[O:3])[CH3:2].[NH:25]=[N+:26]=[N-:27].B(F)(F)F.CCOCC>>[C:1]([O:4][CH2:5][C@:6]12[CH2:23][CH2:22][C@H:21]3[C@@H:11]([CH2:12][CH2:13][CH:14]4[C@:19]3([CH3:20])[CH2:18][CH2:17][C@H:16]([N:25]=[N+:26]=[N-:27])[CH2:15]4)[C@H:10]1[CH2:9][CH2:8][CH2:7]2)(=[O:3])[CH3:2]

Participants

4

Reactant 3

HCID 8000Boron trifluoride etherateHCID 24530Hydrazoic acidHCID 86738341HCID 86738341, compound

Product 1

HCID 86738340HCID 86738340, compound

Procedure

Using the procedures of Example 1, acetoxy-3β hydroxy-14β androstane was treated with an aromatic solution of hydrazoic acid and boron trifluoride etherate.

Sources & evidence

ORD record
ord-cabae02da8024696b001e20e7330197d
Source dataset
uspto-grants-1982_04
Patent number
US04325879

Reaction notes

Loading…