Triphenylphosphine → HCID 20543005, compound

HRID 2286092Notes

Reaction equation

HRID 2286092 reaction equation
[Cl:1][CH2:2][C:3]1[CH:4]=[C:5]2[C:9](=[CH:10][CH:11]=1)[C:8]([CH3:13])([CH3:12])[CH2:7][C:6]2([CH3:15])[CH3:14].[C:16]1([P:22]([C:29]2[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=2)[C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[Cl-:1].[CH3:12][C:8]1([CH3:13])[C:9]2[C:5](=[CH:4][C:3]([CH2:2][P+:22]([C:23]3[CH:24]=[CH:25][CH:26]=[CH:27][CH:28]=3)([C:29]3[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=3)[C:16]3[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=3)=[CH:11][CH:10]=2)[C:6]([CH3:15])([CH3:14])[CH2:7]1

Participants

3

Reactant 2

HCID 11776TriphenylphosphineHCID 20543018HCID 20543018, compound

Product 1

HCID 20543005HCID 20543005, compound

Procedure

In a manner analogous to that described in Example 1, from 5-chloromethyl-1,1,3,3-tetramethyl-indane and triphenylphosphine there can be obtained [1-(1,1,3,3-tetramethyl-5-indanyl)methyl]-triphenylphosphonium chloride.

Sources & evidence

ORD record
ord-d76bd69cbc0a4a58ba6121a83eccc423
Source dataset
uspto-grants-1982_04
Patent number
US04326055

Reaction notes

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