Picric Acid → Ferrous picrate

HRID 2286296Notes

Reaction equation

[Fe:1].[C:2]1([C:16]([OH:17])=[C:12]([N+:13]([O-:15])=[O:14])[CH:11]=[C:7]([N+:8]([O-:10])=[O:9])[CH:6]=1)[N+:3]([O-:5])=[O:4]>>[C:12]1([C:16]([O-:17])=[C:2]([N+:3]([O-:5])=[O:4])[CH:6]=[C:7]([N+:8]([O-:10])=[O:9])[CH:11]=1)[N+:13]([O-:15])=[O:14].[Fe+2:1].[C:12]1([C:16]([O-:17])=[C:2]([N+:3]([O-:5])=[O:4])[CH:6]=[C:7]([N+:8]([O-:10])=[O:9])[CH:11]=1)[N+:13]([O-:15])=[O:14]

Participants

Reactant 2

HCID 6954Picric Acid

HCID 23925Iron

Product 1

HCID 12056057Ferrous picrate

Procedure

adding a +2 iron source to said picric acid solution of step (ii) with stirring to obtain a green iron (II) picrate solution; and

Sources & evidence

ORD record: ord-c33575f378544b4386c4420af096d1c2
Source dataset: uspto-grants-1981_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04265639

Reaction notes

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