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HRID2286304

反应详情

EQUATION

反应方程式

HRID 2286304 的结构方程式

REACTANTS

反应物

2
结构：CC1=CC(=O)CC(C)C1
HCID14291

3,5-Dimethylcyclohex-2-en-1-one

C8H12O

结构：CCOP([O-])OCC
HCID3780918

未命名化合物

PRODUCTS

生成物

2
结构：CC1CC(=O)CC(C)(P(=O)(O)O)C1
HCID23462674

未命名化合物

结构：CCOP(=O)(OCC)C1(C)CC(=O)CC(C)C1
HCID23462678

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cl
溶剂HCID313

Hydrochloric Acid

ClH

PROCEDURE

实验过程

Diethyl 1,3-dimethyl-5-oxocyclohexanephosphonate (B. pt. 120°/0.1 mm) was prepared by the base catalysed addition of diethylphosphite to 3,5-dimethyl-2-cyclohexen-1-one. Hydrolysis of the ester in concentrated HCl gave 1,3-dimethyl-5-oxocyclohexanephosphonic acid as a viscous oil.