Sodium → 3-(4-Hydroxy-3-methoxyphenyl)-2-{[hydroxy(phenyl)methylidene]amino}prop-2-enoic acid

HRID 2286327Notes

Reaction equation

HRID 2286327 reaction equation
[Na].[C:2]([NH:10][C@H:11]([C:22]([OH:24])=[O:23])[CH2:12][C:13]1[CH:18]=[CH:17][C:16]([OH:19])=[C:15]([O:20][CH3:21])[CH:14]=1)(=[O:9])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>>[C:2]([NH:10][C:11](=[CH:12][C:13]1[CH:18]=[CH:17][C:16]([OH:19])=[C:15]([O:20][CH3:21])[CH:14]=1)[C:22]([OH:24])=[O:23])(=[O:9])[C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][CH:8]=1

Participants

3

Reactant 2

HCID 5360545SodiumHCID 12681284HCID 12681284, compound

Product 1

HCID 2846473-(4-Hydroxy-3-methoxyphenyl)-2-{[hydroxy(phenyl)methylidene]amino}prop-2-enoic acid

Procedure

Assay of the resulting solution shows an optical purity of 56.4% corresponding to a 78/22 L/D mixture of the sodium salt of N-benzoyl-3-(4-hydroxy-3-methoxyphenyl)-alanine.

Sources & evidence

ORD record
ord-62896e388b9b496085103b93ce83d602
Source dataset
uspto-grants-1981_05
Patent number
US04265827

Reaction notes

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