Cyclohexanone → HCID 23460418, compound

HRID 2286817Notes

Reaction equation

HRID 2286817 reaction equation
[C:1]([O:5][CH2:6][CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].C(OOC(C)(C)C)(C)(C)C.[C:19]1(=[O:25])[CH2:24][CH2:23][CH2:22][CH2:21][CH2:20]1>>[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH:20]1[CH2:21][CH2:22][CH2:23][CH2:24][C:19]1=[O:25])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 3

HCID 7967CyclohexanoneHCID 8033Di-tert-butyl peroxideHCID 1370211-Propene, 3-(1,1-dimethylethoxy)-

Product 1

HCID 23460418HCID 23460418, compoundYield 60%

Procedure

A solution of 114 g (1 mole) of allyl tert.-butyl ether and 29.2 g (0.2 mole) of di-tert.-butyl peroxide was added over 2 hours to 980 g (10 moles) of cyclohexanone at 140° C., while stirring, and the mixture was then kept at the same temperature for a further hour. Working up the reaction mixture by distillation gave 2-(3-tert-butoxy-prop-1-yl)-cyclohexanone in 60% yield.

Workup

  1. waitthe mixture was then kept at the same temperature for a further hour
  2. distillationWorking up the reaction mixture by distillation

Sources & evidence

ORD record
ord-89fc9969c798402190e976aa577e1186
Source dataset
uspto-grants-1981_05
Patent number
US04268445

Reaction notes

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