Chloral → HCID 23460490, compound

Participants

Reaction Steps

A solution of o-aminobenzyl alcohol (2.4 g.) in toluene (5 ml.) was stirred at ambient temperature while anhydrous chloral (2.0 ml.) was added dropwise. The mixture was stirred for 30 minutes, and evaporated to dryness to yield an oil, which was crystallised from aqueous ethanol to give 1,2-dihydro-2-trichloromethyl-4H-benzo[d]-[1,3]-oxazine, m.p. 90°-92° C.

Provenance & Evidence