Hexane → HCID 54522606, compound

HRID 2286979Notes

Reaction equation

HRID 2286979 reaction equation
[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[O:7])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12].[CH2:14]([NH:30][C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][C:32]=1[N+:37]([O-:39])=[O:38])[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].CCCCCC>C1C=CC=CC=1>[Cl:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([N:30]([CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[C:31]2[CH:36]=[CH:35][CH:34]=[CH:33][C:32]=2[N+:37]([O-:39])=[O:38])=[O:7])=[CH:4][C:3]=1[N+:11]([O-:13])=[O:12]

Participants

5

Reactant 3

HCID 8058HexaneHCID 1234774-Chloro-3-nitrobenzoyl chlorideHCID 54544903HCID 54544903, compound

Product 1

HCID 54522606HCID 54522606, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent2×

Procedure

A solution of 33 g of 4-chloro-3-nitro-benzoyl chloride in 100 ml of benzene is added dropwise in the course of one hour to a solution, which has been heated to the reflux temperature, of 54.3 g of N-n-hexadecyl-2-nitroaniline in 80 ml of benzene. After a further two hours, the reaction has ended. The reaction solution is poured into 600 ml of hexane and the mixture is left to stand overnight. The resulting crystals are filtered off with suction and washed with hexane. This gives 48 g of the compound with a melting point of 83° to 85° C.

Workup

  1. waitthe mixture is left
  2. waitto stand overnight
  3. filtrationThe resulting crystals are filtered off with suction
  4. washwashed with hexane

Sources & evidence

ORD record
ord-941a2e945f764daeb007138236748aef
Source dataset
uspto-grants-1981_05
Patent number
US04268591

Reaction notes

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