HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Bromide → HCID 13019874, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Bromide | HCID 260 | — |
| Reactant | Acetic acid 10-acetoxymethyl-anthracen-9-ylmethyl ester | HCID 613145 | — |
| Reactant | HCID 23460973 | HCID 23460973 | — |
| Product | HCID 13019874 | HCID 13019874 | 72.5% |
Reaction Steps
A mixture of 14 parts of 2-(ethylthio)-1-(4-methylphenyl)-1H-imidazole monohydrochloride and 113 parts of hydrobromic acid solution 48% in glacial acetic is stirred and refluxed for 3 hours. The reaction mixture is evaporated and the residue is dissolved in water. The solution is neutralized with sodium hydrogen carbonate. The precipitated product is filtered off and crystallized from 2-propanol, yielding 8.3 parts (72.5%) of 4-[2-(ethylthio)-1H-imidazol-1yl]phenol; mp. 165.2° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04268680 |
| Source dataset | uspto-grants-1981_05 |
| ORD ID | ord-ded38c6b86b844478728f4b6cf9b99ec |
| Source note | uspto-grants-1981_05 |