Methyl triflate → HCID 15476282, compound

HRID 2288572Notes

Reaction equation

HRID 2288572 reaction equation
[CH:1]1[C:14]2[C:5](=[N:6][C:7]3[C:12]([C:13]=2[C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[O:24](C)[S:25]([C:28]([F:31])([F:30])[F:29])(=[O:27])=[O:26]>C(Cl)Cl>[F:29][C:28]([F:31])([F:30])[S:25]([O-:27])(=[O:26])=[O:24].[CH3:28][N+:6]1[C:5]2[C:14](=[CH:1][CH:2]=[CH:3][CH:4]=2)[C:13]([C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[C:12]2[C:7]=1[CH:8]=[CH:9][CH:10]=[CH:11]2

Participants

4

Reactant 2

HCID 9526Methyl triflateHCID 517916Phenyl acridine-9-carboxylate

Product 1

HCID 15476282HCID 15476282, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Phenyl acridine-9-carboxylate (530 mg, 1.7 mmol) was dissolved in CH2Cl2 (5 mL) under argon and methyl triflate (1 mL, 8.8 mmol) was added. The solution was stirred overnight at room temperature to yield a thick yellow precipitate. This precipitate was filtered, washed with ether and dried to obtain the product as yellow crystals. 1H NMR (acetone-d6) δ 5.22 (s, 3H), 7.47-7.71 (m, 5H), 8.23-9.07 (m, 8H).

Workup

  1. customto yield a thick yellow precipitate
  2. filtrationThis precipitate was filtered
  3. washwashed with ether
  4. customdried

Sources & evidence

ORD record
ord-ccd31068837e4f0483912c6297c5bf4a
Source dataset
uspto-grants-2000_07
Patent number
US06090571

Reaction notes

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