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HRID2288926

反应详情

EQUATION

反应方程式

HRID 2288926 的结构方程式

REACTANTS

反应物

4
结构：CO
HCID887

Methanol

CH4O

结构：CC(C)(C)OC(=O)N=COCNCCC[C@H](N)C(=O)OC(C)(C)C.Cl.N#N
HCID86755535

未命名化合物

结构：CC(C)(C)OC(=O)N[C@@H](CCCCNC#N)C(=O)OC(C)(C)C.N#N
HCID131721879

未命名化合物

结构：CCON=CNCCCC[C@H](NC(=O)OC(C)(C)C)C(=O)OC(C)(C)C.Cl.N#N
HCID178475095

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)N=COCN[C@@H](CCCCN)C(=O)OC(C)(C)C.Cl.N#N
HCID131721877

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClCCl
溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

From 1.6 g (4.89 mmol) N2 -(tert-butoxycarbonyl)-N6 -(cyano)-L-lysine tert-butyl ester was prepared 1.5 g (75%) of foamy solid N2 -(tert-butoxycarbonyl)-N6 -(ethoxyiminomethyl)-L-lysine tert-butyl ester hydrochloride by the method described for N2 -(tert-butoxycarbonyl)-N5 -(iminomethoxymethyl)-L-ornithine tert-butyl ester hydrochloride. TLC (methanol:dichloromethane/1:9) Rf=0.36. Mass spectrum (CI) 360 (MH+, 60%).