1,2-Dichlorobenzene → HCID 14677683, compound

HRID 2289096Notes

Reaction equation

HRID 2289096 reaction equation
C([O:4][C:5]1[CH:10]=[CH:9][C:8]([CH2:11][C:12]([O:14][CH3:15])=[O:13])=[CH:7][CH:6]=1)C=C.Cl[C:17]1[CH:22]=CC=C[C:18]=1Cl>>[CH2:22]([C:10]1[CH:9]=[C:8]([CH2:11][C:12]([O:14][CH3:15])=[O:13])[CH:7]=[CH:6][C:5]=1[OH:4])[CH:17]=[CH2:18]

Participants

3

Reactant 2

HCID 72391,2-DichlorobenzeneHCID 12941055HCID 12941055, compound

Product 1

HCID 14677683HCID 14677683, compound

Procedure

A solution of methyl 4-alloxyphenylacetate (3.1 grams) in dry ortho-dichlorobenzene (50 mL) was refluxed for 25 hours. The solvent was removed under reduced pressure, and the residue was purified by chromatography (silica gel, 50% methylene chloride in hexane) to afford the tittle compound.

Workup

  1. customThe solvent was removed under reduced pressure
  2. customthe residue was purified by chromatography (silica gel, 50% methylene chloride in hexane)
  3. customto afford the tittle compound

Sources & evidence

ORD record
ord-fad1b842688347a0a7dd872f6dfd9aa1
Source dataset
uspto-grants-2000_07
Patent number
US06090836

Reaction notes

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