Dichloromethane → HCID 20231876, compound

Participants

Reaction Conditions

Reaction Steps

To a stirred mixture of 20 g (0.22, 0.2 mole) methyl hydrazinocarboxylate in 150 ml methylene chloride, 14.6 g (0.2 mole) methyl isothiocyanate in 50 ml methylene chloride was added dropwise. The reaction mixture was refluxed at about 40° C. for 0.5 hour, was allowed to stir overnight at ambient temperature, and was refluxed an additional 2 hours. The reaction mixture was cooled, vacuum filtered and the solids were dried to give 27.2 g of the above-identified product.

Provenance & Evidence