Carbon Disulfide → HCID 86741089, compound

Participants

Reaction Steps

To a stirred solution of 4.91 g. of N-(2-hydroxyethyl)morpholine in 250 ml. of anhydrous tetrahydrofuran at room temperature was added 1.79 g. of a 50% dispersion of sodium hydride in mineral oil. A precipitate formed. The mixture was stirred for 30 minutes, and then 2.75 ml. of carbon disulfide was added, causing the initial precipitate to dissolve. The reaction mixture was stirred for 30 minutes during which time a further precipitate formed. To the mixture was added 200 ml. of anhydrous ether, and the precipitate was recovered by filtration. The solid was washed with ether, and dried, to give 8.8 g. of the title compound.

Provenance & Evidence