Chlorodimethylsilane → HCID 13529574, compound

HRID 2292242Notes

Reaction equation

HRID 2292242 reaction equation
[CH2:1]([C:3]([CH2:9][CH3:10])=[C:4]([CH2:7][CH3:8])[CH2:5][CH3:6])[CH3:2].[CH3:11][SiH:12]([CH3:14])[Cl:13].[Al+3].[Cl-].[Cl-].[Cl-]>CCCCC>[CH2:1]([C:3]([Si:12]([CH3:14])([CH3:11])[Cl:13])([CH2:9][CH3:10])[CH:4]([CH2:7][CH3:8])[CH2:5][CH3:6])[CH3:2]

Participants

5

Reactant 3

HCID 66108ChlorodimethylsilaneHCID 1366683,4-Diethyl-3-hexeneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 13529574HCID 13529574, compound

Reagents, catalysts & solvents 1

HCID 8003PentaneSolvent

Procedure

2.1 g of tetraethylethylene, 2 ml (18 mmol) of dimethylchlorosilane and 200 mg of AlCl3 are reacted according to Example 1. After 2 hours, the reaction mixture is diluted with pentane and the precipitate is filtered off. The pentane is stripped from the filtrate in vacuo and the residue is distilled. This gives 2.8 g (80% of theory) of product as a colourless liquid. Boiling point=75°-80° C./0.195 mbar.

Workup

  1. filtrationthe precipitate is filtered off
  2. distillationthe residue is distilled

Sources & evidence

ORD record
ord-63aa4b82a32e498b9d7caa4d6112011f
Source dataset
uspto-grants-1989_01
Patent number
US04801719

Reaction notes

Loading…