Heptanal → HCID 21477974, compound

HRID 2292409Notes

Reaction equation

HRID 2292409 reaction equation
C([Li])CCC.[CH:6](=[O:13])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[F:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][C:16]=1[F:21]>>[F:14][C:15]1[C:16]([F:21])=[CH:17][CH:18]=[CH:19][C:20]=1[CH:6]([OH:13])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 3

HCID 8130HeptanalHCID 97061,2-DifluorobenzeneHCID 178418339Butyllithium

Product 1

HCID 21477974HCID 21477974, compound

Procedure

Quantities: n-butyllithium (50 cm3, 10.0M in hexanes, 0.5 mol), heptanal (57 g, 0.5 mol) and 1,2-difluorobenzene (57 g, 0.5 mol). The experimental procedure was as described in Example 16.

Sources & evidence

ORD record
ord-8a851d4ec5ca4aae8671e365f8157cc0
Source dataset
uspto-grants-1997_11
Patent number
US05683623

Reaction notes

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