Thionyl Chloride → HCID 53883511, compound

HRID 2292466Notes

Reaction equation

HRID 2292466 reaction equation
[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH2:12][C:13]([OH:15])=O.S(Cl)([Cl:18])=O>C(Cl)(Cl)(Cl)Cl>[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH2:12][C:13]([Cl:18])=[O:15]

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 54184109HCID 54184109, compound

Product 1

HCID 53883511HCID 53883511, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

By the method of Example 1, Step E, 18.27 grams (0.073 mole) of 2,3-dichloro-5-nitrophenylacetic acid and 80 mL of thionyl chloride were reacted in 400 mL of carbon tetrachloride, yielding 20.90 grams of 2,3-dichloro-5-nitrophenylacetyl chloride. The NMR was consistent with the proposed structure.

Sources & evidence

ORD record
ord-8afd02ddc08d4631a84bdb464260499d
Source dataset
uspto-grants-1997_11
Patent number
US05683966

Reaction notes

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