2,6-Di-tert-butyl-4-mercaptophenol → 2,6-Di-tert-butyl-4-mercaptophenol

HRID 2292471Notes

Reaction equation

HRID 2292471 reaction equation
[C:1]([C:5]1[CH:6]=[C:7]([SH:16])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])([CH3:4])([CH3:3])[CH3:2].[CH3:17][CH2:18][O:19][C:20](/[N:22]=[N:23]/[C:24]([O:26][CH2:27][CH3:28])=[O:25])=[O:21]>O1CCOCC1>[C:1]([C:5]1[CH:6]=[C:7]([SH:16])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])([CH3:4])([CH3:3])[CH3:2].[N:22]([C:20]([O:19][CH2:18][CH3:17])=[O:21])=[N:23][C:24]([O:26][CH2:27][CH3:28])=[O:25]

Participants

5

Reactant 2

HCID 703702,6-Di-tert-butyl-4-mercaptophenolHCID 5462977Diethyl azodicarboxylate

Product 2

HCID 703702,6-Di-tert-butyl-4-mercaptophenolHCID 220568ethyl N-ethoxycarbonyliminocarbamate

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

Combine 3,5-di-t-butyl-4-hydroxythiophenol (751 mg), diethylazodicarboxylate (496μL, 3.15 mmol) and p-dioxane (5 mL). Place under an argon atmosphere and stir for 2 hours to give a complex of 3,5-di-t-butyl-4-hydroxythiophenol and diethyl azodicarboxylate.

Sources & evidence

ORD record
ord-3ab93d4447a24843820cbea4552c093f
Source dataset
uspto-grants-1997_11
Patent number
US05683982

Reaction notes

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