Sodium Azide → HCID 178432091, compound

HRID 2292739Notes

Reaction equation

HRID 2292739 reaction equation
[CH3:1][C:2]1[N:6]([CH2:7][C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=3[C:20]#[N:21])=[CH:10][CH:9]=2)[C:5]2[CH:22]=[C:23]([C:26]3[N:30]([CH3:31])[C:29]4[CH:32]=[CH:33][CH:34]=[CH:35][C:28]=4[N:27]=3)[CH:24]=[CH:25][C:4]=2[N:3]=1.[N-:36]=[N+:37]=[N-:38].[Na+]>CN(C)C=O>[CH3:1][C:2]1[N:6]([CH2:7][C:8]2[CH:9]=[CH:10][C:11]([C:14]3[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=3[C:20]3[NH:38][N:37]=[N:36][N:21]=3)=[CH:12][CH:13]=2)[C:5]2[CH:22]=[C:23]([C:26]3[N:30]([CH3:31])[C:29]4[CH:32]=[CH:33][CH:34]=[CH:35][C:28]=4[N:27]=3)[CH:24]=[CH:25][C:4]=2[N:3]=1

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 21479095HCID 21479095, compound

Product 1

HCID 178432091HCID 178432091, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 41 from 4'-[[2-methyl-6-(1-methylbenzimidazol-2-yl)-benzimidazol-1-yl]methyl]-2-cyano-biphenyl and sodium azide in dimethylformamide.

Sources & evidence

ORD record
ord-89534f757c5e4dcd9d09fa8a4a23c5fe
Source dataset
uspto-grants-1997_11
Patent number
US05684029

Reaction notes

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