5,6,7,8-Tetrahydro-5,5,8,8-tetramethyl-2-naphthylmethanol → Allyl 4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylmethyloxycarbonyl)benzoate

HRID 2294552Notes

Reaction equation

HRID 2294552 reaction equation
[CH2:1]([O:4][C:5]([C:7]1[CH:15]=[CH:14][C:10]([C:11](O)=[O:12])=[CH:9][CH:8]=1)=[O:6])[CH:2]=[CH2:3].[CH3:16][C:17]1([CH3:31])[CH2:26][CH2:25][C:24]([CH3:28])([CH3:27])[C:23]2[CH:22]=[C:21]([CH2:29][OH:30])[CH:20]=[CH:19][C:18]1=2>>[CH3:16][C:17]1([CH3:31])[CH2:26][CH2:25][C:24]([CH3:27])([CH3:28])[C:23]2[CH:22]=[C:21]([CH2:29][O:30][C:11]([C:10]3[CH:14]=[CH:15][C:7]([C:5]([O:4][CH2:1][CH:2]=[CH2:3])=[O:6])=[CH:8][CH:9]=3)=[O:12])[CH:20]=[CH:19][C:18]1=2

Participants

3

Reactant 2

HCID 144256215,6,7,8-Tetrahydro-5,5,8,8-tetramethyl-2-naphthylmethanolHCID 183498554-(Allyloxycarbonyl)benzoic acid

Product 1

HCID 21474529Allyl 4-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylmethyloxycarbonyl)benzoate

Procedure

In a manner similar to Example 4(c), by reaction of 2.06 g (10 mmol) of 4-(allyloxycarbonyl)benzoic acid with 2.18 g (10 mmol) of 5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylmethanol, 2.8 g (70%) of allyl ester are obtained in the form of a translucent oil.

Workup

  1. customare obtained in the form of a translucent oil

Sources & evidence

ORD record
ord-cb685f53cfee4d05a2a35381f87c10d6
Source dataset
uspto-grants-1997_11
Patent number
US05688817

Reaction notes

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