m-Chloroperbenzoic acid → HCID 178441440, compound

HRID 2294890Notes

Reaction equation

HRID 2294890 reaction equation
[Br:1][C:2]1[CH:3]=[C:4]2[NH:11][C:10]([CH2:12][CH2:13][CH2:14][CH3:15])=[N:9][C:5]2=[N:6][C:7]=1[CH3:8].ClC1C=CC=C(C(OO)=[O:24])C=1>C(Cl)Cl>[Br:1][C:2]1[CH:3]=[C:4]2[NH:11][C:10]([CH2:12][CH2:13][CH2:14][CH3:15])=[N:9][C:5]2=[N+:6]([O-:24])[C:7]=1[CH3:8]

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 22100349HCID 22100349, compound

Product 1

HCID 178441440HCID 178441440, compoundYield 97%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

7.8 g (29.1 mmole) of the compound obtained in step 4 was dissolved in 50 ml of methylene chloride and to the resulting solution was added 8.8 g (43.6 mmole) of 85% m-chloroperbenzoic acid. The resultant was stirred for 16 hours at room temperature and filtered to get a solid, which was washed with ethyl ether (12 ml×3) to obtain 8.0 g of the title compound (yield 97%).

Workup

  1. filtrationfiltered
  2. customto get a solid, which
  3. washwas washed with ethyl ether (12 ml×3)

Sources & evidence

ORD record
ord-534eb6e4a39140019444dbf493b98cfd
Source dataset
uspto-grants-1997_11
Patent number
US05691348

Reaction notes

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