Hydrogen Peroxide → HCID 20475521, compound

HRID 2295388Notes

Reaction equation

HRID 2295388 reaction equation
[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[N:5]=[C:4]([NH:9][C:10]([C:12]2[C:13]([CH2:22][S:23]([CH3:25])=[O:24])=[C:14]([S:18]([NH2:21])(=[O:20])=[O:19])[CH:15]=[CH:16][CH:17]=2)=[O:11])[N:3]=1.[OH:26]O>C(O)(=O)C>[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[N:5]=[C:4]([NH:9][C:10]([C:12]2[C:13]([CH2:22][S:23]([CH3:25])(=[O:26])=[O:24])=[C:14]([S:18]([NH2:21])(=[O:19])=[O:20])[CH:15]=[CH:16][CH:17]=2)=[O:11])[N:3]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 20475520HCID 20475520, compound

Product 1

HCID 20475521HCID 20475521, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of 0.1 g (0.2 mmol) of [N-(4,6-dimethylpyrimidinyl)aminocarbonyl]-o-methylsulfinylmethylbenzenesulfonamide and 0.3 ml of 30% hydrogen peroxide in 5 ml of acetic acid was stirred at room temperature for 3 days. The resulting white solid precipitate was filtered to afford 30 mg of the desired product: m.p. 222°-225° C.

Workup

  1. filtrationThe resulting white solid precipitate was filtered

Sources & evidence

ORD record
ord-ed158e0b35054060973b1d47ee9375d3
Source dataset
uspto-grants-1984_01
Patent number
US04424377

Reaction notes

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