Hydrochloric Acid → HCID 131713358, compound

HRID 2295400Notes

Reaction equation

HRID 2295400 reaction equation
[Cl:1][Pt-2:2](Cl)(Cl)Cl.[K+].[K+].[CH:8]([C:10]1[CH:15]=[C:14]([CH3:16])[N:13]=[C:12]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][N:18]=2)[CH:11]=1)=[CH2:9].[ClH:23]>O>[Cl:23][C:15]1[C:10]([CH:8]=[CH2:9])=[C:11]([Cl:1])[C:12]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][N:18]=2)=[N:13][C:14]=1[CH3:16].[Pt:2]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 61440Dipotassium tetrachloroplatinateHCID 15606559HCID 15606559, compound

Product 1

HCID 131713358HCID 131713358, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 0.830 g (2×10-3 mol) of potassium tetrachloroplatinate in 100 ml of water, 0.432 g (2.2×10-3 mol) of 4-vinyl-6-methyl-2,2'-bipyridine and 4 ml of 2 N hydrochloric acid is boiled for 30 minutes. After cooling, the yellow crystals which have precipitated are filtered off with suction. After concentration of the filtrate, further product is obtained. The product is recrystallised from N,N-dimethylacetamide/water.

Workup

  1. temperatureAfter cooling
  2. customthe yellow crystals which have precipitated
  3. filtrationare filtered off with suction
  4. customAfter concentration of the filtrate, further product is obtained
  5. customThe product is recrystallised from N,N-dimethylacetamide/water

Sources & evidence

ORD record
ord-3b42da23babe41fe813ab350d9fe202d
Source dataset
uspto-grants-1984_01
Patent number
US04424359

Reaction notes

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