Toluene → HCID 54405367, compound

HRID 2295707Notes

Reaction equation

HRID 2295707 reaction equation
ClCC=CC=C.[CH2:7]([C:10]([CH2:12][CH2:13][CH3:14])=[O:11])[CH2:8][CH3:9].[OH-].[K+].[C:17]1([CH3:23])[CH:22]=[CH:21]C=[CH:19][CH:18]=1>>[CH2:8]([CH:7]([CH2:21][CH:22]=[C:17]([CH3:23])[CH:18]=[CH2:19])[C:10](=[O:11])[CH2:12][CH2:13][CH3:14])[CH3:9]

Participants

5

Reactant 4

HCID 1140TolueneHCID 14797Potassium HydroxideHCID 312464-HeptanoneHCID 53837795HCID 53837795, compound

Product 1

HCID 54405367HCID 54405367, compound

Procedure

According to the procedure described in Example 1, from 116.6 g of 1-chloro-2,4-pentadiene and 114.2 g of dipropyl ketone (heptan-4-one) in the presence of 200 g of powdered potassium hydroxide in 600 ml of toluene there are obtained 91.9 g of crude 5-ethyl-8-methyl-7,9-decadien-4-one which are subjected to a fractional distillation.

Sources & evidence

ORD record
ord-93aaf191434c4ccf998c1493c033fe2c
Source dataset
uspto-grants-1984_01
Patent number
US04426321

Reaction notes

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