Ethanol → HCID 86596485, compound

HRID 229886Notes

Reaction equation

[CH2:1]([OH:3])C.[S:4](=[O:8])(=[O:7])([OH:6])[OH:5].[CH:9]([Cl:12])([Cl:11])[Cl:10]>>[CH:9]([Cl:12])([Cl:11])[Cl:10].[CH3:1][OH:3].[S:4](=[O:6])(=[O:5])([OH:8])[OH:7]

Participants

Reactant 3

HCID 702Ethanol

HCID 1118Sulfuric Acid

HCID 6212Chloroform

Product 1

HCID 86596485HCID 86596485, compound

Procedure

A colorless solid (0.078 g, yield: 82.1%) was obtained through a reaction conducted as in example 2 except that the reactants were replaced by the compound (117) prepared in example 17 (0.1 g), ethanol (66.6 mL), chloroform (100 mL), and sulfuric acid (36 N, 0.3 mL), and the reaction time was adjusted to 96 hours. IR analysis of the product revealed the existence of an absorption band that suggested an acetoxy group at 1740 cm−1. 1H-NMR analysis revealed the product consists of a compound (138) and the compound (117) (content of compound (138): 90.1 mol %).

Sources & evidence

ORD record: ord-df6cf5c9112a4711be733d64d75a3fef
Source dataset: uspto-grants-2009_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07563917B2

Reaction notes

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