1-Methyl-2(1H)-pyridinethione → HCID 10192947, compound

HRID 2300993Notes

Reaction equation

HRID 2300993 reaction equation
[CH3:1][N:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]1=[S:8].[CH3:9][C:10]1[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][C:11]=1[CH2:12][Cl:13]>C1(C)C=CC=CC=1>[Cl-:13].[CH3:9][C:10]1[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][C:11]=1[CH2:12][S:8][C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][N+:2]=1[CH3:1]

Participants

4

Reactant 2

HCID 162771-Methyl-2(1H)-pyridinethioneHCID 69987Benzene, 2-(chloromethyl)-1,4-dimethyl-

Product 1

HCID 10192947HCID 10192947, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Conditions

Temperature
70 °C

Procedure

A mixture of 5.0 g of 1-methyl-2(1H)-pyridinethione and 6.2 g of 2,5-dimethylbenzyl-chloride in 40 ml of toluene was heated for five hours at 70° C. A pale yellow solid was filtered from the cooled mixture. Yield was 5 g having a melting point of 130-137° C. NMR and infrared spectra were consistent with the structure.

Workup

  1. filtrationA pale yellow solid was filtered from the cooled mixture

Sources & evidence

ORD record
ord-656b2a20a9224861a9cd97145866e476
Source dataset
uspto-grants-2002_12
Patent number
US06498254B1

Reaction notes

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