Chloride → 1-(Chlorosulfanyl)dodecane

HRID 2301906Notes

Reaction equation

HRID 2301906 reaction equation
[CH2:1]([SH:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Cl-:14]>C(Cl)(Cl)Cl>[CH2:1]([S:13][Cl:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 312ChlorideHCID 81951-Dodecanethiol

Product 1

HCID 156071481-(Chlorosulfanyl)dodecane

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

To a solution of dodecane thiol (1.00 mL, 4.17 mmol, Aldrich) in 20 mL CHCl3 was added suliryl chloride (0.74 mL, 9.19 mmol, Aldrich), and the regulting mixture was stirred at room temperature for 18 h. Removal of solvent (aspirator), afforded dodecansulfenyl chloride that was determined to be sufficiently pure by 1H NMR.

Workup

  1. customRemoval of solvent (aspirator)

Sources & evidence

ORD record
ord-b0efa6536ab549168c50a7543b527c4e
Source dataset
uspto-grants-2002_08
Patent number
US06429200B1

Reaction notes

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