HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → Ethyl 5'-[3,4-bis(1-phenylmethanoyloxymethyl)-benzyloxy]-2'-methylbiphenyl-4-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 3,4-Bis(benzoyloxymethyl)benzyl bromide | HCID 22345618 | — |
| Reactant | Ethyl 5'-hydroxy-2'-methylbiphenyl-4-carboxylate | HCID 22606906 | — |
| Product | Ethyl 5'-[3,4-bis(1-phenylmethanoyloxymethyl)-benzyloxy]-2'-methylbiphenyl-4-carboxylate | HCID 22606888 | — |
Reaction Steps
In a manner similar to that of Example 1(i), by reaction of 3.07 g (12 mmol) of ethyl 5′-hydroxy-2′-methylbiphenyl-4-carboxylate with 6.7 g (15 mmol) of 3,4-bis(benzoyloxymethyl)benzyl bromide and 2 mg (14 mmol) of potassium carbonate, the desired product is obtained in the form of a colourless oil (m=5.7 g; Y=77%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06831106B1 |
| Source dataset | uspto-grants-2004_12 |
| ORD ID | ord-877b03b68bf74828bc829fba7aed0cf9 |
| Source note | uspto-grants-2004_12 |