Aluminium lithium hydride → HCID 17934664, compound

HRID 2307577Notes

Reaction equation

HRID 2307577 reaction equation
[CH2:1]([C:3]1([C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:19]=[CH:18][CH:17]=[C:16]([CH:20]=[O:21])[CH:15]=3)=[C:10]([CH3:22])[CH:9]=2)[O:7][CH2:6][CH2:5][O:4]1)[CH3:2].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH2:1]([C:3]1([C:8]2[CH:13]=[CH:12][C:11]([C:14]3[CH:19]=[CH:18][CH:17]=[C:16]([CH2:20][OH:21])[CH:15]=3)=[C:10]([CH3:22])[CH:9]=2)[O:4][CH2:5][CH2:6][O:7]1)[CH3:2]

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 22606926HCID 22606926, compound

Product 1

HCID 17934664HCID 17934664, compound

Procedure

In a manner similar to that of Example 20(e), by reaction of 4.5 g (15.2 mmol) of 4′-(2-ethyl-[1,3]dioxolan-2-yl]-2′-methylbiphenyl-3-carbaldehyde with 760 mg (20 mmol) of lithium aluminium hydride, the desired product is obtained in the form of a colourless oil (m=4.4 g, Y=97%).

Sources & evidence

ORD record
ord-f64981d19a734eea934650552bc6f6e8
Source dataset
uspto-grants-2004_12
Patent number
US06831106B1

Reaction notes

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