Potassium Carbonate → HCID 17934633, compound

HRID 2307589Notes

Reaction equation

HRID 2307589 reaction equation
Br[C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[C:10]([OH:14])[CH:9]=2)=[C:4]([CH3:15])[CH:3]=1.Br[CH2:17][C:18]1[CH:19]=[C:20]([C:28]([O:30]C)=O)[C:21](=[CH:26][CH:27]=1)[C:22]([O:24]C)=O.[C:32](=[O:35])([O-])[O-].[K+].[K+]>>[OH:30][CH2:28][C:20]1[CH:19]=[C:18]([CH:27]=[CH:26][C:21]=1[CH2:22][OH:24])[CH2:17][O:14][C:10]1[CH:9]=[C:8]([C:5]2[CH:6]=[CH:7][C:2]([CH:32]([OH:35])[C:4]([CH3:15])([CH3:5])[CH3:3])=[CH:3][C:4]=2[CH3:15])[CH:13]=[CH:12][CH:11]=1

Participants

4

Reactant 3

HCID 11430Potassium CarbonateHCID 22606860HCID 22606860, compoundHCID 232556044-Bromomethylphthalic acid dimethyl ester

Product 1

HCID 17934633HCID 17934633, compound

Procedure

In a manner similar to that of Example 1(i), by reaction of 11.8 g (44.8 mmol) of 4′-bromo-2′-methylbiphenyl-3-ol with 14.2 g (49 mmol) of dimethyl 4-bromomethylphthalate and 6.5 g (47 mmol) of potassium carbonate, the desired product is obtained in the form of a yellow oil (m=16.4 g; Y=78%).

Sources & evidence

ORD record
ord-9b0b2311d2154b489e87b975f4f86439
Source dataset
uspto-grants-2004_12
Patent number
US06831106B1

Reaction notes

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