Sodium → HCID 86593395, compound

HRID 2308056Notes

Reaction equation

HRID 2308056 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[C:7]([O:9][CH3:10])[CH:6]=[CH:5][C:4]=1[C:11]#[CH:12].[CH3:13][O:14][C:15]1[CH:22]=[C:21]([O:23][CH3:24])[CH:20]=[CH:19][C:16]=1[CH2:17][SH:18].[Na]>>[CH3:1][O:2][C:3]1[CH:8]=[C:7]([O:9][CH3:10])[CH:6]=[CH:5][C:4]=1/[CH:11]=[CH:12]\[CH:11]([S:18][CH:17](/[CH:12]=[CH:11]\[C:4]1[CH:5]=[CH:6][C:7]([O:9][CH3:10])=[CH:8][C:3]=1[O:2][CH3:1])[C:16]1[CH:19]=[CH:20][C:21]([O:23][CH3:24])=[CH:22][C:15]=1[O:14][CH3:13])[C:4]1[CH:5]=[CH:6][C:7]([O:9][CH3:10])=[CH:8][C:3]=1[O:2][CH3:1]

Participants

4

Reactant 3

HCID 5360545SodiumHCID 10702639Benzenemethanethiol, 2,4-dimethoxy-HCID 15184633Benzene, 1-ethynyl-2,4-diMethoxy-

Product 1

HCID 86593395HCID 86593395, compound

Procedure

A solution of 2,4-dimethoxyphenylacetylene (0.02 mol), 2,4-dimethoxybenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) is subjected to the General Procedure to form (Z)-2,4-dimethoxystyryl-2,4-dimethoxybenzylsulfide. The title compound is obtained following oxidation of the sulfide, according to the General Procedure.

Sources & evidence

ORD record
ord-b5ee0824a9004bfaaeb2b3d975f86e62
Source dataset
uspto-grants-2004_12
Patent number
US06833480B2

Reaction notes

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